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Fresh Grad Lands Job as Real Estate Agent With Help from Professional Writers

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Exam 1 Module 1-6

Navigation   » List of Schools  »  Southern California University of Health Sciences  »  Organic Chemistry  »  OCHEM 316 – Organic Chemistry II  »  Summer 2022  »  Exam 1 Module 1-6

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Below are the questions for the exam with the choices of answers:

Question #1
Why is pyridine included in the reaction of an acid chloride and an amine or alcohol?
A  Pyridine will absorb the heat of the reaction
B  Pyridine will protonate the carbonyl of the acid chloride, making it more reactive
C  Pyridine will neutralize the acid by-product of the reaction
D  Pyridine will deprotonate the amine or alcohol, making it a better nucleophile
Question #2
From the list below, pick the compound that does not react with acetyl chloride.
A  Ammonia
B  Triethyl amine
C  Benzoic acid
D  Isopropyl alcohol
Question #3
All of the following contain sp2 hybridized atoms in their functional group except
A  a carboxylic acid
B  an anhydride
C  an aldehyde
D  a nitrile
Question #4
Which of the following statements about amides is true?
A  Amides react with methyl alcohol in the presence of an acid catalyst to form an ester
B  Amides are hydrolyzed in acid or base to form carboxylic acids or carboxylate anions
C  Amides react with thionyl chloride to form the acid chloride
D  Amides do not react under any conditions. They are inert compounds
Question #5
Which of the following is the most polar organic compound?
A  CH3COOH
B  CH3CH2CHO
C  CH3CH2CH2OH
D  CH3CH2CH2CH3
Question #6
What two groups make up the carboxylic acid group (RCOOH)?
A  Carbon dioxide and hydrogen
B  Carbonyl oxide and hydrogen
C  Carbon monoxide and hydroxyl
D  Carbonyl and hydroxyl
Question #7
What is the overall charge of the amino acid, alanine, at pH = 10?
A  no overall charge
B  -2
C  1
D  -1
Question #8
Using IR spectroscopy, how can you tell the difference between a ketone and an aldehyde?
A  A ketone has no C-H stretches
B  An aldehyde has two C-H stretches between 2700-2850 cm−1
C  An aldehyde has a carbonyl stretch at 1820 cm−1
D  A ketone has no carbonyl stretch at 1720 cm−1
Question #9
Which reagent can be used to reduce an acid chloride to an aldehyde?
A  LiAlH4
B  LiAlH(OtBu)3
C  FeCl3
D  NaBH4
Question #10
What is the purpose of a silyl ether?
A  To protect alcohols from organometallic reagents and other reagents
B  To protect ketones from organometallic reagents and other reagents
C  To protect esters from organometallic reagents and other reagents
D  To prevent the formation of carboxylic acids
Question #11
Which of the following information is primarily obtained from an IR spectrum?
A  Conjugated  p system present in a compound
B  Molecular weight of a compound
C  Functional groups present in a compound
D  The carbon and hydrogen framework of a compound
Question #12
Why does an alkyne carbon–carbon triple bond vibrate at a higher wavenumber than an alkene carbon–carbon double bond?
A  It is stronger
B  It has fewer hydrogens
C  It is weaker
D  It makes a less stable cation
Question #13
What would be the molecular formula of rose oxide which contains C, H, and O and has two degrees of unsaturation and a molecular ion in its mass spectrum at m/z =154?
A  C8H10O3
B  C10H2O2
C  C10H18O
D  C9H14O2
Question #14
You observe a compound that exhibits a mass spectrum with peak at 160 and a peak at 162, both of equal intensity. This compound contains
A  two bromine atoms
B  one iodine atom
C  two chlorine atoms
D  one bromine atom
Question #15
Which of the following statements about the base peak of a mass spectrum is always true?
A  None of these
B  The base peak corresponds to the molecular ion
C  The base peak corresponds to the most abundant ion
D  The base peak corresponds to the lowest m/z
Question #16
Pentane, C5H12, would have which of the following fragments in its mass spectrum?
m/z
I 29
II 43
III 57
A  All of the choices are correct
B  I
C  III
D  II
Question #17
Butane, C4H10, would have which of the following fragments in its mass spectrum?
m/z
I 15
II 29
III 57
A  I and II
B  II
C  III
D  I
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“Kudos to the team for a job well done.  I am sincerely appreciative of the time and effort you gave on my resume.  You did not only help me land the job I had always been dreaming of but you also made me realize how important adding those specific keywords to my resume!  Cheers!

Manush
Fresh Graduate
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