Exam 3

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Question #1

A solution containing CaCl2 is mixed with a solution of Li2C2O4 to form a solution that is 2.1 × 10-5 M in calcium ion and 4.75 × 10-5 M in oxalate ion. What will happen once these solutions are mixed forming the concentrations given above? Ksp (CaC2O4) = 2.3 × 10-9.

A There is not enough information to determine.

B No precipitant will form since Qsp < Ksp

C Nothing will happen since both calcium chloride and lithium oxalate are soluble compounds.

D A precipitate will form since Qsp > Ksp for calcium oxalate.

E Nothing will happen since calcium oxalate is extremely soluble.

Question #2

If the pKa of HCHO2 is 3.74 and the pH of an HCHO2/NaCHO2 solution is 3.54, which of the following is TRUE?

A It is not possible to make a buffer of this pH from HCHO2 and NaCHO2.

B [HCHO2] > [NaCHO2]

C [HCHO2] < [NaCHO2]

D [HCHO2] = [NaCHO2]

E Does not have enough information to tell

Question #3

Which of the following titrations result in a acidic solution at the equivalence point?

A NaOH titrated with HNO3, HClO3 titrated with NaOH

B HBr titrated with Ba(OH)2, NaOH titrated with HNO3

C HI titrated with NaCH3CO2 , Ba(NO2)2 titrated with HCl

D None of the above

Question #4

To simulate the pH of blood, which is 7.29, an undergraduate researcher in a biology lab produced a buffer solution by dissolving sodium dihydrogen phosphate and disodium hydrogen phosphate together in an aqueous solution. What mole ratio of Na2HPO4/NaH2PO4 did she need to use? Ka2 = 6.2 x 10–8 and Ka3=3.6 x 10–13

A 1.2

B 1

C 0.9

D 1.6

E None of the choices are correct

F 0.96

Question #5

An unknown student takes 25.0 mL sample of an unknown weak base solution with a an unknown concentration and titrates it with H2SO4 solution. At half-equivalence point the pH is 11.20. It takes 16mL of H2SO4 to reach an equivalence point. What would be the concentration of the unknown weak base sample ________ M if the pOH at equivalence point is 8.12.

A 0.452

B 0.654

C 1.211

D 1.069

E 0.935

Question #6

What volume (in mL) of 0.15M NaOH to you have to add to 50.7 mL of 0.15 M acetic acid (CH3CO2H) to prepare a buffer solution with a pH of 5.02? The pKa of acetic acid is 4.74.

A 33.25

B 40.25

C 25.28

D 39.17

E 28.74

Question #7

A 15.0 mL sample of 0.723 M HClO4 is titrated with a 0.135M Ba(OH)2 solution. The H3O+ concentration after the addition of 75.00mL of Ba(OH)2 is ________ M.

A 4.6 × 10-13

B 1.0 × 10-7

C 2.9 × 10-13

D 2.2 x 10–2 M

E 9.6×10-14

Question #8

A 25.0 mL solution of quinine was titrated with 1.00 M Sulfuric acid, H2SO4. It was found that the solution contained 110 mmoles of quinine (a week base). What would be the pOH at equivalence point. Quinine is monobasic with pKb = 5.10.

A 9.51

B 5.1

C None of the choices are correct

D 4.38

E 9.62

F 8.9

Question #9

Which of the following acids has the weakest conjugate base?
0.1 M HBO, pKa = 2.43
0.1 M HA, pKa = 4.55
0.1 M HMO, pKa = 8.23
0.1 M HST, pKa = 11.89

A HMO

B HST

C pure water

D HA

E HBO

Question #10

What is the pH of your best liquid soap made from a fatty acid (HA) that has a pKa value of 4.0? The concentration of the active ingredient for the solution, a fatty acid conjugate base (NaA), is 0.23 M NaA.

A 5.48

B 9.23

C 8.68

D 6.78

E 8.08

Question #11

The conjugate acid of H2PO4 – is __________

A H2PO4

B H3PO4

C H3O+

D HPO4-2

E none of the above

Question #12

Arrange the following 0.10 M aqueous solutions in order of increasing pH (Low pH to high pH): NaOH, HBr, NaCH3CO2, KBr, NH4Br.

A NaOH, NaCH3CO2, KBr, NH4Br, HBr

B NaOH, NaCH3CO2, NH4Br, KBr, HBr

C HBr, NH4Br, KBr, NaCH3CO2, NaOH

D HBr, KBr, NH4Br, NaCH3CO2, NaOH

Question #13

If the pOH of an aqueous H2SO4 solution is 12
Would the pOH of solution in part A increase, decrease or remain the same if the water evaporates on a hot day

A decrease

B increase

C remain the same if the water evaporates on a hot day

Question #14

If the pOH of an aqueous H2SO4 solution is 12
What would be the concentration of H2SO4 ?

A 0.05

B 0.005

C 0.008

D 0.015

Question #15

The acid-dissociation constants of phosphorous acid (H3PO3) are Ka1 = 7.5 × 10-3, Ka2 = 6.2 × 10-8, and Ka3 = 4.2 × 10-13 at 25.0°C. Which dissociation constants would you use to solve for the pH of 0.5M solution of Na3PO3?

A Kb3 and Ka2

B Kb3 and Ka1

C Kb2 and Ka3

D Ka1

E Kb1 and Ka2

F Kb3

Question #16

A BrØnsted-Lowry base is defined as a substance that __________.

A decreases [H+] when placed in H2O

B acts as a proton acceptor

C increases [OH-] when placed in H2O

D acts as a proton donor

E increases Ka when placed in H2O

Question #17

Which one of the following, A–D, is correct?

A NaHSO3 is a stronger base than NaHSO4.

B K2SO3 is a weaker base than KHSO3.

C Na2HPO4 is a stronger acid than NaH2PO4.

D K2CO3 is a weaker base than KHCO3.

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