Final Exam

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Question #1

Which represents the greatest mass?

A 1.0 mol Fe

B 1.0 mol Al

C all the same

D 1.0 mol Zn

E 1.0 mol Cu

Question #2

The oxidation product of a primary alcohol is

A a ketone.

B an acid.

C an ether.

D an alkene.

E a tertiary alcohol.

Question #3

The most characteristic reaction of the alkenes is

A reduction.

B addition and elimination.

C substitution.

D addition.

E oxidation.

Question #4

If temperature and pressure are held constant, the volume and number of moles of a gas are

A not enough information given

B directly proportional

C inversely proportional

D independent of each other

E equal

Question #5

How many electrons are in the third principal energy level (n = 3) of one atom of Fe?

A none of these

B 18

C 14

D 8

E 2

Question #6

At 1 atm of pressure and a temperature of 0°C, which phase(s) of H2O can exist?

A ice and water vapor

B water only

C ice only

D ice and water

E water vapor only

Question #7

Perform the indicated conversion: 2.63 X 103 cal = _______________ J

A 1.10 X 104 J

B 1.59 x 10–3 J

C 6.29 X 105 J

D 629 J

E 11.0 J

Question #8

Which of the following is an incorrect designation for an atomic orbital?

A 2p

B 2d

C 4f

D 1s

E 3s

Question #9

True or false? Reduction is a gain of electrons.

A FALSE

B TRUE

Question #10

If you mix 20.0 mL of a 3.00 M sugar solution with 30.0 mL of a 5.30 M sugar solution, you will end up with a sugar solution of ________.

A 10.95 M

B 0.166 M

C 7.30 M

D 4.38 M

E 4.15 M

Question #11

You have 25.00 mL of a 0.1000 M sugar solution. How much water must be added to make a 0.01042 M solution?

A 214.9 mL

B 26.1 mL

C 22.4 mL

D 239.9 mL

E 2.61 mL

Question #12

The alkaline earth metals have how many valence electrons?

A 2

B 3

C 7

D 1

E 8

Question #13

True or false? The law of conservation of enery states that energy can be converted from one form to another but can be neither created nor destroyed.

A TRUE

B FALSE

Question #14

Which of the following has a double C-O bond and a single C-O bond?

A alcohol

B ketone

C aldehyde

D amine

E ester

Question #15

The state of matter for an object that has a definite volume but not a definite shape is

A solid

B liquid

C mixed

D elemental

E gaseous

Question #16

A solution with a pH of 2.17 is

A neutral

B basic

C acidic

Question #17

The number of protons in a given nucleus determines the

A atomic number.

B number of protons.

C number of isotopes.

D number of electrons.

E mass number.

Question #18

An aqueous solution of sodium carbonate is reacted with an aqueous solution of calcium chloride.

Identify the solid in the balanced equation.

A CaCO3

B Na2CO3

C There is no solid formed when the two solutions are mixed.

D NaCl

E CaCl2

Question #19

A given set of d orbitals consists of ______________ orbital(s).

A 5

B 3

C 6

D 1

Question #20

The number of significant figures in 0.074100 × 10–4 is

A 3

B 6

C 4

D 7

E 5

Question #21

The air in the inner tube of the tire of a racing bike has a pressure of 110.2 psi. Convert this pressure to atm.

A 1620 atm

B 1.088 atm

C 0.1450 atm

D 7.497 atm

E 110.2 atm

Question #22

Choose the state of water in which the water molecules are farthest apart on average.

A steam (vapor)

B all the same

C liquid

D ice (solid)

Question #23

If you were to heat pentanoic acid and 2-butanol with a strong acid, you would most likely discover in your flask:

A a ketone

B an alkane

C an aldehyde

D an ester

E an amine

Question #24

The number of unpaired electrons in a nitrogen atom is

A 3

B 7

C 5

D 6

E 4

Question #25

A solution has [OH–] = 2.8 X 10–7 M. The [H+] in this solution is

A 2.8X 107 M

B 3.6 X 107 M

C 3.6 X 10–8 M

D 2.8 X 107 M

Question #26

A solution with a pH of 2 is how many times more acidic as a solution with a pH of 3?

A 10

B 2

C 100

D 0.7

E 5

Question #27

Name the following:

CH3C ≡ CCH2CH2Cl

A 5-chloro-2pentyne

B 2-chloro-5pentyne

Question #28

True or false? The calorie is defined as the amount of energy (heat) required to raise the temperature of one gram of water by one degree Celsius.

A TRUE

B FALSE

Question #29

The reaction HCl(aq) + KOH(aq) → H2O(l) + KCl(aq) is a(n) ______________ reaction.

A acid-base

B single-replacement

C none of these

D precipitation

E oxidation-reduction

Question #30

True or false? N2 is an example of a covalent bond.

A TRUE

B FALSE

Question #31

Which of the following compounds contains an ionic bond?

A NaCl

B SO2

C O2

D HCl(g)

E CCl4

Question #32

The oxidation product of a secondary alcohol is

A a ketone.

B an ester.

C an acid.

D an aldehyde.

E a tertiary alcohol.

Question #33

When an electron in the ground state absorbs energy, it goes to a(n) ______________ state.

A excited

B ionic

C frenetic

D stable

E lower

Question #34

The complete combustion of heptane, C7H16, which is a volatile hydrocarbon, yields carbon dioxide and water:
__ C7H16 + __ O2 → __ CO2 + __ H2O
The coefficient of oxygen in the balanced equation is

A 9

B 13

C 15

D 11

E 8

Question #35

The best answer to report for 131.00 – 31.9904 is

A 99.0.

B 99.01.

C 99.010.

D 99.0096.

E 99

Question #36

The total mass of a solution is 171.5 g. The solvent mass is 125.2 g. What is the mass percent of the solute?

A 27.0%

B 38.0%

C 73.0%

D 18.1%

E Not enough information is given.

Question #37

Which of the following compounds contains one or more covalent bonds?

A BaBr2

B Cs2O

C CO2

D CaO

E NaCl

Question #38

The elements chlorine and iodine have similar chemical properties because they

A are in the same chemical period

B none of these

C have the same number of electrons in their outer energy levels

D have the same number of stable isotopes

E are both metals

Question #39

Which of the following will yield a carboxylic acid upon oxidation?

A a cycloalkane

B an aldehyde

C a secondary alcohol

D a ketone

E tertiary alcohol

Question #40

Chemical reactions involving alkanes in which hydrogen atoms are removed and the product is an unsaturated hydrocarbon are called

A polymerization reactions.

B addition reactions.

C substitution reactions.

D dehydrogenation reactions.

E combustion reactions.

Question #41

A substance that, when dissolved in water, produces a solution that conducts electric current very efficiently is called

A none of these

B a strong ion

C an electrical solute

D a weak electrolyte

E a strong electrolyte

Question #42

How many protons, electrons, and neutrons, respectively, does 127I have?

A 53, 74, 53

B 74, 53, 127

C 53, 53, 127

D 53, 127, 74

E 53, 53, 74

Question #43

H2CCHCH2N(CH3)2 is

A an alkene and a tertiary amine.

B an alkyne and a tertiary amine.

C an alkene and a primary amine.

D an alkyne and a secondary amine.

Question #44

There are three isotopes of carbon differing with respect to

B number of protons.

C neutrons.

D electron configuration.

E nuclear charge.

F atomic number.

Question #45

True or false? Arrhenius postulated that acids produce hydrogen ions in aqueous solution, whereas bases produce hydroxide ions.

A FALSE

B TRUE

Question #46

True or false? CH4 has ionic bonds.

A TRUE

B FALSE

Question #47

The chemical formula for iron(III) sulfide is

A Fe2S3.

B Fe3(SO3)2.

C Fe2(SO3)3.

D Fe2(SO4)3.

Question #48

3.03 mol of CO2 at STP will occupy

A 8.93 × 10–2 L

B 33.9 L

C 67.9 g

D 74.1 L

E 67.9 L

Question #49

Oxidation of a primary alcohol results in a(n) __________ and oxidation of a secondary alcohol results in a(n) _________.

A aldehyde, ketone

B ketone, aldehyde

C amine, carboxylic acid

D carboxylic acid, amine

E ester, ether

Question #50

True or false? The equation N2(g) + 3H2(g) → 2NH3(g) can be interpreted by saying that 1 mol of N2 reacts with 3 mol of H2 to form 2 mol of NH3.

A FALSE

B TRUE

Question #51

Which of the following statements is/are correct?

A In a basic solution,[OH-] > [H+]

B In an acidic solution, [H+] > [OH-], In a basic solution,[OH-] > [H+], and In a neutral solution, [H+] = [OH-] .

C In an acidic solution, [H+] > [OH-]

D In a neutral solution, [H+] = [OH-]

E None of the above statements are correct.

Question #52

The formula for potassium carbonate is

A P2CO3.

B K2C.

C P2C.

D K2CO3.

E Po2CO3.

Question #53

A 2.2-mol sample of KClO3 was decomposed according to the equation 2KClO3(s) → 2KCl(s) + 3O2(g) How many moles of O2 are formed?

A 2.2 mol

B 1.8 mol

C 1.5 mol

D 3.3 mol

E 1.1 mol

Question #54

1s22s22p63s23p64s23d7 is the electron configuration for which of the following atoms?

A Ar

B Co

C Fe

D Cr

E Ca

Question #55

Heat is typically measured in

A joules

B °C

C grams

D °F

Question #56

Calculate the heat given off when 101.4 g of copper cools from 155.0oC to 23.0oC. The specific heat of copper is 0.385 J/g oC.

A none of these

B 6.05 × 103 J

C 8.98 × 102 J

D 3.48 × 104 J

E 5.15 × 103 J

Question #57

In the reaction 2Cs(s) + Cl2(g) → 2CsCl(s), the chlorine is ______________.

A oxidized

B synthesized

C electrolyzed

D reduced

Question #58

Identify the type of organic compound shown: (CH3)3N

A aldehyde

B ester

C ketone

D amine

Question #59

Which of the following elements is most similar to chlorine?

A Br

B H

C He

D Na

E Hg

Question #60

Which particle has the smallest mass?

A helium nucleus

B proton

C neutron

D electron

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