Final Exam

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Question #1

Which represents the greatest mass?

A 1.0 mol Cu

B 1.0 mol Zn

C 1.0 mol Al

D 1.0 mol Fe

E all the same

Question #2

The oxidation product of a primary alcohol is

A a tertiary alcohol.

B a ketone.

C an alkene.

D an acid.

E an ether.

Question #3

The most characteristic reaction of the alkenes is

A oxidation.

B reduction.

C addition and elimination.

D substitution.

E addition.

Question #4

If temperature and pressure are held constant, the volume and number of moles of a gas are

A not enough information given

B inversely proportional

C equal

D directly proportional

E independent of each other

Question #5

How many electrons are in the third principal energy level (n = 3) of one atom of Fe?

A none of these

B 14

C 18

D 8

E 2

Question #6

At 1 atm of pressure and a temperature of 0°C, which phase(s) of H2O can exist?

A ice and water

B water vapor only

C water only

D ice only

E ice and water vapor

Question #7

Perform the indicated conversion: 2.63 X 103 cal = _______________ J

A 6.29 X 105 J

B 1.10 X 104 J

C 629 J

D 1.59 x 10–3 J

E 11.0 J

Question #8

Which of the following is an incorrect designation for an atomic orbital?

A 1s

B 4f

C 3s

D 2d

E 2p

Question #9

True or false? Reduction is a gain of electrons.

A FALSE

B TRUE

Question #10

If you mix 20.0 mL of a 3.00 M sugar solution with 30.0 mL of a 5.30 M sugar solution, you will end up with a sugar solution of ________.

A 4.38 M

B 7.30 M

C 4.15 M

D 0.166 M

E 10.95 M

Question #11

You have 25.00 mL of a 0.1000 M sugar solution. How much water must be added to make a 0.01042 M solution?

A 22.4 mL

B 2.61 mL

C 26.1 mL

D 239.9 mL

E 214.9 mL

Question #12

The alkaline earth metals have how many valence electrons?

A 3

B 2

C 1

D 7

E 8

Question #13

True or false? The law of conservation of enery states that energy can be converted from one form to another but can be neither created nor destroyed.

A FALSE

B TRUE

Question #14

Which of the following has a double C-O bond and a single C-O bond?

A aldehyde

B ester

C amine

D alcohol

E ketone

Question #15

The state of matter for an object that has a definite volume but not a definite shape is

A elemental

B mixed

C gaseous

D liquid

E solid

Question #16

A solution with a pH of 2.17 is

A neutral

B acidic

C basic

Question #17

The number of protons in a given nucleus determines the

A number of isotopes.

B mass number.

C atomic number.

D number of electrons.

E number of protons.

Question #18

An aqueous solution of sodium carbonate is reacted with an aqueous solution of calcium chloride.

Identify the solid in the balanced equation.

A CaCl2

B Na2CO3

C There is no solid formed when the two solutions are mixed.

D CaCO3

E NaCl

Question #19

A given set of d orbitals consists of ______________ orbital(s).

A 6

B 1

C 3

D 5

Question #20

The number of significant figures in 0.074100 × 10–4 is

A 4

B 3

C 7

D 6

E 5

Question #21

The air in the inner tube of the tire of a racing bike has a pressure of 110.2 psi. Convert this pressure to atm.

A 110.2 atm

B 1.088 atm

C 0.1450 atm

D 7.497 atm

E 1620 atm

Question #22

Choose the state of water in which the water molecules are farthest apart on average.

A steam (vapor)

B liquid

C ice (solid)

D all the same

Question #23

If you were to heat pentanoic acid and 2-butanol with a strong acid, you would most likely discover in your flask:

A a ketone

B an alkane

C an aldehyde

D an ester

E an amine

Question #24

The number of unpaired electrons in a nitrogen atom is

A 7

B 4

C 6

D 3

E 5

Question #25

A solution has [OH–] = 2.8 X 10–7 M. The [H+] in this solution is

A 3.6 X 10–8 M

B 2.8 X 107 M

C 2.8X 107 M

D 3.6 X 107 M

Question #26

A solution with a pH of 2 is how many times more acidic as a solution with a pH of 3?

A 10

B 2

C 0.7

D 5

E 100

Question #27

Name the following:

CH3C ≡ CCH2CH2Cl

A 5-chloro-2pentyne

B 2-chloro-5pentyne

Question #28

True or false? The calorie is defined as the amount of energy (heat) required to raise the temperature of one gram of water by one degree Celsius.

A TRUE

B FALSE

Question #29

The reaction HCl(aq) + KOH(aq) → H2O(l) + KCl(aq) is a(n) ______________ reaction.

A acid-base

B single-replacement

C precipitation

D none of these

E oxidation-reduction

Question #30

True or false? N2 is an example of a covalent bond.

A FALSE

B TRUE

Question #31

Which of the following compounds contains an ionic bond?

A O2

B NaCl

C CCl4

D SO2

E HCl(g)

Question #32

The oxidation product of a secondary alcohol is

A an aldehyde.

B an ester.

C an acid.

D a ketone.

E a tertiary alcohol.

Question #33

When an electron in the ground state absorbs energy, it goes to a(n) ______________ state.

A frenetic

B lower

C ionic

D excited

E stable

Question #34

The complete combustion of heptane, C7H16, which is a volatile hydrocarbon, yields carbon dioxide and water:
__ C7H16 + __ O2 → __ CO2 + __ H2O
The coefficient of oxygen in the balanced equation is

A 8

B 9

C 15

D 13

E 11

Question #35

The best answer to report for 131.00 – 31.9904 is

A 99.0096.

B 99.0.

C 99.010.

D 99

E 99.01.

Question #36

The total mass of a solution is 171.5 g. The solvent mass is 125.2 g. What is the mass percent of the solute?

A Not enough information is given.

B 18.1%

C 27.0%

D 73.0%

E 38.0%

Question #37

Which of the following compounds contains one or more covalent bonds?

A CO2

B Cs2O

C BaBr2

D NaCl

E CaO

Question #38

The elements chlorine and iodine have similar chemical properties because they

A are both metals

B none of these

C are in the same chemical period

D have the same number of stable isotopes

E have the same number of electrons in their outer energy levels

Question #39

Which of the following will yield a carboxylic acid upon oxidation?

A a cycloalkane

B an aldehyde

C a secondary alcohol

D tertiary alcohol

E a ketone

Question #40

Chemical reactions involving alkanes in which hydrogen atoms are removed and the product is an unsaturated hydrocarbon are called

A combustion reactions.

B dehydrogenation reactions.

C addition reactions.

D polymerization reactions.

E substitution reactions.

Question #41

A substance that, when dissolved in water, produces a solution that conducts electric current very efficiently is called

A an electrical solute

B a strong electrolyte

C a weak electrolyte

D a strong ion

E none of these

Question #42

How many protons, electrons, and neutrons, respectively, does 127I have?

A 74, 53, 127

B 53, 127, 74

C 53, 53, 74

D 53, 74, 53

E 53, 53, 127

Question #43

H2CCHCH2N(CH3)2 is

A an alkyne and a tertiary amine.

B an alkyne and a secondary amine.

C an alkene and a primary amine.

D an alkene and a tertiary amine.

Question #44

There are three isotopes of carbon differing with respect to

A electron configuration.

B number of protons.

C nuclear charge.

D neutrons.

E atomic number.

Question #45

True or false? Arrhenius postulated that acids produce hydrogen ions in aqueous solution, whereas bases produce hydroxide ions.

A TRUE

B FALSE

Question #46

True or false? CH4 has ionic bonds.

A FALSE

B TRUE

Question #47

The chemical formula for iron(III) sulfide is

A Fe2(SO3)3.

B Fe2(SO4)3.

C Fe3(SO3)2.

D Fe2S3.

Question #48

3.03 mol of CO2 at STP will occupy

A 67.9 L

B 8.93 × 10–2 L

C 33.9 L

D 67.9 g

E 74.1 L

Question #49

Oxidation of a primary alcohol results in a(n) __________ and oxidation of a secondary alcohol results in a(n) _________.

A aldehyde, ketone

B amine, carboxylic acid

C ester, ether

D carboxylic acid, amine

E ketone, aldehyde

Question #50

True or false? The equation N2(g) + 3H2(g) → 2NH3(g) can be interpreted by saying that 1 mol of N2 reacts with 3 mol of H2 to form 2 mol of NH3.

A TRUE

B FALSE

Question #51

Which of the following statements is/are correct?

A In a neutral solution, [H+] = [OH-]

B In an acidic solution, [H+] > [OH-]

C In a basic solution,[OH-] > [H+]

D In an acidic solution, [H+] > [OH-], In a basic solution,[OH-] > [H+], and In a neutral solution, [H+] = [OH-] .

E None of the above statements are correct.

Question #52

The formula for potassium carbonate is

A K2CO3.

B Po2CO3.

C K2C.

D P2C.

E P2CO3.

Question #53

A 2.2-mol sample of KClO3 was decomposed according to the equation 2KClO3(s) → 2KCl(s) + 3O2(g) How many moles of O2 are formed?

A 1.8 mol

B 1.5 mol

C 3.3 mol

D 1.1 mol

E 2.2 mol

Question #54

1s22s22p63s23p64s23d7 is the electron configuration for which of the following atoms?

A Fe

B Cr

C Ca

D Co

E Ar

Question #55

Heat is typically measured in

A grams

B °C

C joules

D °F

Question #56

Calculate the heat given off when 101.4 g of copper cools from 155.0oC to 23.0oC. The specific heat of copper is 0.385 J/g oC.

A none of these

B 5.15 × 103 J

C 6.05 × 103 J

D 3.48 × 104 J

E 8.98 × 102 J

Question #57

In the reaction 2Cs(s) + Cl2(g) → 2CsCl(s), the chlorine is ______________.

A oxidized

B synthesized

C reduced

D electrolyzed

Question #58

Identify the type of organic compound shown: (CH3)3N

A amine

B ketone

C ester

D aldehyde

Question #59

Which of the following elements is most similar to chlorine?

A H

B Br

C He

D Hg

E Na

Question #60

Which particle has the smallest mass?

A electron

B helium nucleus

C neutron

D proton

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